Versatile Postmodification of Conjugated Microporous Polymers Using Thiol-yne Chemistry
ACS Macro Letters
Baris Kiskan, Jens Weber
Radical thiol-yne chemistry is used for the modification of microporous networks with aliphatic alcohols. The degree of functionalization can be tuned by varying the reacted amount of thiol. Porosity analysis indicates that the microporosity can be preserved within a certain range, however, a decrease in pore size is observed.