RESEARCH HIGHLIGHT

Calix[4]pyrroles with bulky substituents and their anion binding studies

TURKISH JOURNAL OF CHEMISTRY

2017

Ahmet AKAR, Abdullah AYDOĞAN

TOC

Calix[4]pyrrole derivatives with bulky substituents at their meso-positions were synthesized via mixed condensation of pyrrole with cyclohexanone and acetophenone derivatives. Anion binding studies, carried out by isothermal titration calorimetry in 1,2-dichloroethane with Cl and CH3CO2 anions in the form of their tetrabutylammonium salts, revealed that these new calix[4]pyrrole derivatives can bind the aforementioned anions as effectively as the unsubstituted “parent” system, octamethylcalix[4]pyrrole. Structural characterizations of new calix[4]pyrroles were carried out by using 1H and 13C NMR spectroscopy corroborated with mass spectrometry

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